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Materials, Methods & Technologies, Volume 3, 2009

CHARGE TRANSFER IN THE LITHIUM CORROSION FILMS FORMED IN THE SOLUTIONS ON THE BASIS OF NITROMETHANE
Andrey P. Kurbatov, Alina K. Galeyeva
Pages: 523-530
Publié: 1 Jan 2009
Vues: 418
Téléchargements: 55
Résumé: Processes of polarization of films formed on the lithium electrode at corrosion in solutions of lithium bromide and iodide in the pyridine-nitromethane mix were investigated. It was shown, that the kind of polarizing curves was defined by speed of potential sweep and exposition time. The current restriction by a spatial charge was revealed at injection of additional carriers into the film, especially at high speeds of sweep. At small sweep speeds and power failure indemnification in the solution the process is limited by charge transfer in high intensity fields. The assumption of double injection of additional carriers into the film was made.
Mots-clés : charge transfer, lithium corrosion film
Citer cet article : Andrey P. Kurbatov, Alina K. Galeyeva. CHARGE TRANSFER IN THE LITHIUM CORROSION FILMS FORMED IN THE SOLUTIONS ON THE BASIS OF NITROMETHANE. Journal of International Scientific Publications: Materials, Methods & Technologies 3, 523-530 (2009). https://www.scientific-publications.net/en/article/1003510/
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