NEW EFFICIENT METHOD FOR THE SYNTHESIS OF THE WATER-SOLUBLE 1,2–[B12H10(OH)2]2– ANION WITH THE EXOPOLYHEDRAL B-OH REACTION SITES FOR THE SUBSEQUENT MODIFICATION IN DEVELOPING BNCT PREPARATIONS
Aleksandr I. Ogarkov, Andrei S. Chernyavskii, Sergey G. Sakharov, Konstantin A. Solntsev
Strony: 48-53
Opublikowano: 2 Jun 2014
Wyświetlenia: 3,923
Pobrania: 997
Streszczenie: An original method for synthesis of a water-soluble derivative of the 1,2-[B12H10(OH)2] 2– boron cluster anion using alkaline hydrolysis of the products of interaction of bis(tetrabutylammonium) dodecahydro-closododecaborate (2–) with the melt of benzene-1,2-dicarboxylic acid in an inert atmosphere is developed. The synthesized compounds were identified with the help of the elemental analysis and IR and 11B spectroscopy of the nuclear magnetic resonance (NMR). It is shown that regioselectivity under the considered synthesis condition depends on the geometry of the selected synthesis reagent, namely, benzene-1,2-dicarboxylic acid.
Słowa kluczowe: dodecahydro-closo-dodecaborate anion (2–), carboxylation, three-dimensional aromaticity, regioselectivity, nmr spectroscopy, ir spectroscopy
Cytowanie artykułu: Aleksandr I. Ogarkov, Andrei S. Chernyavskii, Sergey G. Sakharov, Konstantin A. Solntsev. NEW EFFICIENT METHOD FOR THE SYNTHESIS OF THE WATER-SOLUBLE 1,2–[B12H10(OH)2]2– ANION WITH THE EXOPOLYHEDRAL B-OH REACTION SITES FOR THE SUBSEQUENT MODIFICATION IN DEVELOPING BNCT PREPARATIONS. Journal of International Scientific Publications: Materials, Methods & Technologies 8, 48-53 (2014). https://www.scientific-publications.net/en/article/1000145/
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